Answer 4_6_7

When cadmium light is viewed through a diffraction grating having 500 lines per millimetre, the following spectral lines were observed at the stated angles.

 

                        Angle (o)                      Colour

                        18.78                           red

                        14.74                           green

                        13.89                           light blue

                        13.53                           dark blue

 

Find the wavelength of these lines.  Find the other angles at which spectral lines would be observed.                                                                                                                                      

Work out the spacing: d = 0.001 m = 2.00  ´ 10-6 m (P)

                                             500 m-1

Formula:  l = d sin q

                            n

For all of these angles, n = 1, so we can ignore it (P).

 

For red light,

                   l = 2.00 ´ 10-6 ´ sin 18.78o  = 6.44 ´ 10-7 m = 644 nm (P)

We can do similar calculations to find the wavelengths of all the other spectral lines:

 

            green - 509 nm; light blue - 480 nm; dark blue - 468 nm. (P)

To work out the second order angles we need to use:

 

                             sin q = nl

                                       d

For red light:

                             sin q  = 2 ´ 6.44 ´ 10-7 m = 0.644 (P)

                                          2.00 × 10-6 m

 

Þ q = sin -1 0.644 = 40.09o (not equal to 2 × 18.78o) (P)

 

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